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Reference type: Journal
Authors: Chen L, Lv XD, Dai JD, Sun L, Huo PW, Li CX, Yan YS
Article Title: Direct Detection of Potential Pyrethroids in Yangtze River via an Imprinted Multilayer Phosphorescence Probe.
Publication date: 2018
Journal: Analytical Sciences
Volume: 34
Issue: (5)
Page numbers: 613-618.
DOI: 10.2116/analsci.17P497
Alternative URL: https://www.jstage.jst.go.jp/article/analsci/34/5/34_613/_article/-char/en

Abstract: A novel tailored multilayer probe for monitoring potential pyrethroids in the Yangtze River was proposed. The room-temperature phosphorescence method was applied to realize a detection strategy that is superior to the fluorescence method. Efficient Mn-doped ZnS quantum dots with uniform size of 4.6 nm were firstly coated with a mesoporous silica to obtain a suitable intermediate transition layer, then an imprinted layer containing bifenthrin specific recognition sites was anchored. Characterizations verified the multilayer structure convincingly and the detection process relied on the electron transfer-induced fluorescence quenching mechanism. Optional detection time and standard detection curve were obtained within a concentration range from 5.0 to 50 μmol L-1. The stability was verified to be good after 12 replicates. Feasibility of the probe was proved by monitoring water samples from the Zhenjiang reach of the Yangtze River. The probe offers promise for direct bifenthrin detection in unknown environmental water with an accurate and stable phosphorescence analysis strategy
Template and target information: bifenthrin
Author keywords: Room temperature phosphorescence probes, molecular imprinting technique, semiconductor nanocrystals, bifenthrin detection, Yangtze River sample


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