Authors: Muratsugu S
, Baba H
, Tanimoto T
, Sawaguchi K
, Ikemoto S
, Tasaki M
, Terao Y
, Tada M
Chemoselective epoxidation of cholesterol derivatives on a surface-designed molecularly imprinted Ru-porphyrin catalyst.
Publication date: 2018
Journal: Chemical Communications
Abstract: A new molecularly imprinted Ru-porphyrin complex catalyst on a SiO2 support was designed, prepared, and characterized in a step-by-step manner for the C5=C6 epoxidation of cholesterol derivatives. High chemoselectivity for the C5=C6 epoxidation of cholesterol derivatives without protecting the 3-position OH group and other oxidizable functional groups was achieved on the molecularly imprinted catalyst
Template and target information: cholesterol derivatives
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