MIPs logo MIPdatabase      MIP2020 Conference logo Use this space
Custom Search
Reference type: Journal
Authors: Li L, Liang ZP, Zhou QS, Chen R, Lin SL
Article Title: Preparation and characterization of imidacloprid molecular imprinted polymers.
Publication date: 2013
Journal: Food and Fermentation Industries
Volume: 39
Issue: (12)
Page numbers: 79-84.
Alternative URL: http://caod.oriprobe.com/articles/41417454/Preparation_and_characterization_of_imidacloprid_molecular_imprinted_p.htm

Abstract: Molecular imprinted polymers (MIPs) for imidacloprid were prepared by suspension polymerization method, in which acrylic acid (AA) was used as a functional monomer, and ethylene glycol dimethacrylate (EGDMA) was used as a crosslinker in methanol. The effects of template molecule, regarding the functional monomer molar ratio, dosage of crosslinkers and solvents on the morphology and adsorption properties were investigated. The optimized formula was obtained by an orthogonal test L 9 (33) as follows: imidacloprid 2 mmol, EGDMA 50 mmol, methanol 150 mL, AIBN 0.05 g, AA 8 mmol. The results showed that the polymer has largest adsorption capacity (361 mg/g) and recovery ratio (94. 6%). Scatchard analysis showed that there were two kinds of sorption active sites in MIPs, and the binding capacity (Qmax) and dissociation contents (Kd) were Qmax1 = 188.29 mg/g, Kd1 = 16.42 mg/L and Qmax2 = 610.08 mg/g, Kd2 = 714.29 mg/L respectively. The molecular imprinted polymers exhibited a good selectivity and a large adsorption capacity compared to the imidacloprid materials.
Template and target information: imidacloprid
Author keywords: Imidacloprid, Molecularly imprinted polymers, suspension polymerization, Adsorption properties

  mipdatabase.com logo special offer joke shirt  Lab Rat Periodic table bag  HE-MAN polymer chemistry shirt

Molecules Special Issue call      Appeal for information


Join the Society for Molecular Imprinting
Logo of the Society for Molecular Imprinting

New items RSS feed
new items RSS feed  View latest updates

Sign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent e-mail alerts.
Click here to go to the sign-up page.

Is your name elemental or peptidic? Enter your name and find out by clicking either of the buttons below!
Other products you may like:
view listings for MIP books on eBay:

Mickey Mouse 90th Anniversary banner