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Reference type: Journal
Authors: Kang YF, Zhang L, Lai QH, Lin CW, Wu KL, Dang LT, Li L
Article Title: Molecularly imprinted polymer based on metal-organic frameworks: synthesis and application on determination of dibutyl phthalate.
Publication date: 2021
Journal: Polymer-Plastics Technology and Materials
Volume: 60
Issue: (1)
Page numbers: 60-69.
DOI: 10.1080/25740881.2020.1786582

Abstract: The molecular surface imprinted graft copolymer of metal-organic framework MOF-5 with methacrylic acid were prepared by free radical polymerization with dibutyl phthalate as the template molecule using initiator of azobisisobutyronitrile as adsorption system. The prepared MIPs@MOF-5 were characterized by fourier transform infrared spectroscopy, scanning electron microscopy, Brunner-Emmet-Teller measurements, adsorption isotherms, kinetics and selectivity experiments, which showed higher specificity, sensitivity, stability, and better adsorption performance. The results suggested that MIPs@MOF-5 had two sites of adsorption behavior and can recognize sensitively and selectively the template molecules. Moreover, the MIPs@MOF-5 was successfully applied to the analysis of tap water sample
Template and target information: dibutyl phthalate
Author keywords: Dibutyl phthalate, molecularly imprinted polymer, metal-organic framework MOF-5, adsorption

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