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Reference type: Journal
Authors: Huang WH, Jiang PF, Yin XF, Zhang LM, Zhao S, Zhou HD, Ni XN, Xu WZ
Article Title: Selective enrichment-release of trace dibutyl phthalate via molecular-imprinting based photo-controlled switching followed by high-performance liquid chromatography analysis.
Publication date: 2021
Journal: Journal of Separation Science
Volume: 44
Issue: (2)
Page numbers: 513-520.
DOI: 10.1002/jssc.202000950

Abstract: A novel intelligent photo-controlled molecularly imprinted polymers were synthesized, based on the magnetic core-shell structure, with 4-[(4-methacryloyloxy) phenylazo] benzenesulfonic acid as the functional monomer and ethylene glycol dimethyl acrylate as the cross-linking agent. Subsequently, a series of light-controlled enrichment-release performance showed that it only took about 30 and 10 min to reach the equilibrium photosensitive characteristic peak, respectively. The photo-controlled polymers could intelligently select target molecules, the maximum adsorption capacity for dibutyl phthalate was 3.88 mg/g. However, the adsorption capacity for its structural analogue dicyclohexyl phthalate was only 0.88 mg/g. The Freundlich and Langmuir isothermal equations were discussed for the specific enrichment process. Finally, the photo-controlled molecularly imprinted polymers were successfully applied to the selective detection of dibutyl phthalate, with the recovery rate of 95.4-98.4%. It could be used for the analysis of trace dibutyl phthalate in actual samples
Template and target information: dibutyl phthalate
Author keywords: Dibutyl phthalate, Magnetic core-shell, Molecularly imprinted polymers, photo-controlled, plasticizers


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