MIPs logo MIPdatabase      MIP2024 Conference banner, website is now open, register on site for important updates   
Custom Search
Reference type: Journal
Authors: Huang WH, Jiang PF, Yin XF, Zhang LM, Zhao S, Zhou HD, Ni XN, Xu WZ
Article Title: Selective enrichment-release of trace dibutyl phthalate via molecular-imprinting based photo-controlled switching followed by high-performance liquid chromatography analysis.
Publication date: 2021
Journal: Journal of Separation Science
Volume: 44
Issue: (2)
Page numbers: 513-520.
DOI: 10.1002/jssc.202000950

Abstract: A novel intelligent photo-controlled molecularly imprinted polymers were synthesized, based on the magnetic core-shell structure, with 4-[(4-methacryloyloxy) phenylazo] benzenesulfonic acid as the functional monomer and ethylene glycol dimethyl acrylate as the cross-linking agent. Subsequently, a series of light-controlled enrichment-release performance showed that it only took about 30 and 10 min to reach the equilibrium photosensitive characteristic peak, respectively. The photo-controlled polymers could intelligently select target molecules, the maximum adsorption capacity for dibutyl phthalate was 3.88 mg/g. However, the adsorption capacity for its structural analogue dicyclohexyl phthalate was only 0.88 mg/g. The Freundlich and Langmuir isothermal equations were discussed for the specific enrichment process. Finally, the photo-controlled molecularly imprinted polymers were successfully applied to the selective detection of dibutyl phthalate, with the recovery rate of 95.4-98.4%. It could be used for the analysis of trace dibutyl phthalate in actual samples
Template and target information: dibutyl phthalate
Author keywords: Dibutyl phthalate, Magnetic core-shell, Molecularly imprinted polymers, photo-controlled, plasticizers


  Periodic table Stew - the chemical formula for stew shirt  Periodic table Bag bag  Meerkat somebody mention coffee mug






 

Join the Society for Molecular Imprinting
Logo of the Society for Molecular Imprinting

New items RSS feed
new items RSS feed  View latest updates

Sign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent e-mail alerts.
Click here to go to the sign-up page.


Is your name elemental or peptidic? Enter your name and find out by clicking either of the buttons below!
Other products you may like:
view listings for MIP books on eBay:



Mickey Mouse 90th Anniversary banner