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Reference type: Journal
Authors: Li JW, Cheng HM
Article Title: Ion-imprinted modified molecular sieves show the efficient selective adsorption of chromium(VI) from aqueous solutions.
Publication date: 2020
Journal: RSC Advances
Volume: 10
Issue: (71)
Page numbers: 43425-43431.
DOI: 10.1039/D0RA08501D

Abstract: Molecular sieve 5A was modified with (3-aminopropyl) triethoxysilane (APTES) as the support matrix, on which 4-VP was used as the ionic imprinting group. The as-prepared IIZMS-APTES was applied as the adsorbent for the recovery of chromium(VI) from aqueous solutions. The adsorbent was characterized via Fourier transform infrared spectroscopy (FT-IR), scanning electronic microscopy (SEM), and X-ray diffraction (XRD). The influences of adsorption time, concentration of the ions, initial pH, and temperature on the adsorption performance to Cr(VI) were investigated. The selectivity and reusability of IIZMS-APTES are also evaluated. The results showed that the maximum adsorption capacity reached 56.46 mg g-1 when the initial concentration of metal ions was at 100 mg L-1 at pH 2 and 30 ℃ . The adsorption process followed the pseudo-second-order kinetic model and Langmuir adsorption isotherm model. The IIZMS-APTES exhibits an efficient selective adsorption of Cr(VI) from aqueous solutions
Template and target information: Chromium ion, Cr(VI)


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