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Reference type: Journal
Authors: Kou YC, Wu T, Zheng H, Kadasala NR, Yang S, Guo CZ, Chen L, Liu Y, Yang JH
Article Title: Recyclable Magnetic MIP-Based SERS Sensors for Selective, Sensitive, and Reliable Detection of Paclobutrazol Residues in Complex Environments.
Publication date: 2020
Journal: ACS Sustainable Chemistry & Engineering
Volume: 8
Issue: (38)
Page numbers: 14549-14556.
DOI: 10.1021/acssuschemeng.0c05065

Abstract: In this work, a molecularly imprinted polymer (MIP)-based SERS sensor for selective, sensitive, quantitative, and recyclable detection of paclobutrazol residues in complex environments has been proposed. In this strategy, Fe3O4@SiO2GÇôAu@Ag (FSAA) nanocomposites with tunable Au@Ag interparticle gaps are constructed. Then, by tuning the Au@Ag nanogaps and investigating the SERS enhancement mechanism of FSAA, we achieve the optimal SERS substrate, FSAA-40. After combining with MIPs, we can selectively detect paclobutrazol in soil with a detection limit of 0.075 μg/g. When the paclobutrazol concentration ranges from 0.075 to 12.75 μg/g, the SERS intensity shows a linear correlation, which opens the possibility for quantitative detection. Our magnetic MIP-based SERS sensor can be easily separated, efficiently recycled, and expanded to more universal environments, which demonstrates a promising future in food and environmental safety
Template and target information: paclobutrazol
Author keywords: SERS, MIPs, magnetic MIP-based SERS sensor, Recyclability, paclobutrazol


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