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Abstract: This study presents novel chemoresistive reduced graphene oxide-ion-imprinted polymer (IIP-rGO)-based sensors for detection of lead (Pb2+) ions. The ion-imprinted polymer was synthesized by bulk polymerization and modified with a variable amount of rGO incorporated to form an IIP-rGO composite. The amount of rGO in the polymer matrix affected the sensor's relative response, and 1:3 mass ratio produced excellent results, with a consistent trend as the concentration of Pb2+ ions increased in the solution. The decrease in relative resistance (Δ R/Ro) followed an exponential decay relationship between the Δ R/Ro response and the concentration of Pb2+ ions in aqueous solutions. After solving the exponential decay function, it is observed that the sensor has the upper limit of Δ R/Ro >1.7287 μg L-1, and the limit of detection of the sensor is 1.77 μg L-1. A nonimprinted polymer (NIP)-based sensor responded with a low relative resistance of the same magnitude although the concentration was varied. The response ratio of the IIP-based sensor to the NIP-based sensor (Δ R/Ro)IIP/(Δ R/Ro)NIP as a function of the concentration of Pb2+ ions in the solution shows that the response ratios recorded a maximum of around 22 at 50 μg L-1 and then decreased as the concentration increased, following an exponential decay function with the minimum ratio of 2.09 at 200 μg L-1 but never read 1. The sensor showed excellent selectivity against the bivalent cations Mn2+, Fe2+, Sn2+, and Ti2+. The sensor was capable of exhibiting 90% Δ R/Ro response repeatability in a consecutive test
Template and target information: lead ion, Pb(II)