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Reference type: Journal
Authors: Yoshikawa M, Hotta N, Kyoumura J, Osagawa Y, Aoki T
Article Title: Chiral recognition sites from carbonyldioxyglyceryl moiety by an alternative molecular imprinting.
Publication date: 2005
Journal: Sensors and Actuators B: Chemical
Volume: 104
Issue: (2)
Page numbers: 282-288.
DOI: 10.1016/j.snb.2004.05.025

Abstract: A novel candidate polymeric material bearing 5-membered cyclic carbonate moiety, poly[(2-oxo-1,3-dioxolan-4-yl)methyl methacrylate-co-acrylonitrile], was converted into a chiral recognition material by adopting Ac--Trp or Ac--Trp as a print molecule. The molecularly imprinted polymer showed chiral recognition ability, and the material imprinted by the D-isomer of Ac-Trp recognized the D-isomer in preference to the corresponding L-isomer and vice versa. The formation of the chiral recognition site was confirmed by the apparent adsorption isotherms of the molecularly imprinted materials
Template and target information: Ac-Trp
Author keywords: chiral recognition, molecular imprinting, molecular recognition, surface plasmon resonance


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