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Reference type: Journal
Authors: Karakhanov EA, Maksimov AL, Zhuchkova AY, Filippova TY, Karapetyan LM
Article Title: Molecular imprinting as a method for the creation of cyclodextrin-based supramolecular catalysts used in the Wacker oxidation of unsaturated compounds.
Publication date: 2005
Journal: Petroleum Chemistry
Volume: 45
Issue: (2)
Page numbers: 79-86.

Abstract: Macrocyclic ligands produced by modification of cyclodextrins with toluene-2,4-diisocyanate and N,Ar-methylenebisacrylamide in the presence and in the absence of templates were used as components of catalyst systems in the Wacker oxidation of unsaturated compounds. The following substrates were used as templates: dodecene-1, hexadecene-1, and p-tert-butylstyrene. The activity of catalyst systems containing β-cyclodextrins modified in the presence of templates was shown to be considerably higher than for the same systems containing a macroligand produced without a template. (originally published as: Neftekhimiya 45 (2) , pp. 97-104)
Template and target information: dodecene-1, hexadecene-1, p-tert-butylstyrene


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