Authors: Nakagawa H
, Muraki M
, Miura Y
, Kinoshita M
Spacer effect in the template polycondensation of nucleotide analogs with diamines.
Publication date: 1982
Journal: Makromolekulare Chemie-Macromolecular Chemistry And Physics
Abstract: The template effect of polymers containing the adenine residue, 6, bound to a polystyrene backbone via a spacer group, on the polycondensation of active esters of thymine, 1, and theophylline, 2, with piperazine was studied in pyridine/methylene chloride or DMF. Template polymers accelerated the polycondensation of 1 with diamines by a factor of 5-20, but the polycondensation of 2 with piperazine showed no considerable template effect.
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