Authors: Huang XD
, Chen XG
, Ou JJ
, Tang SW
, Kong L
, Zou HF
Chromatographic properties for enantiomeric separation of amino acid derivatives on the molecularly imprinted monoliths.
Publication date: 2004
Journal: Chinese Journal of Chromatography
Alternative URL: http://www.chrom-china.com/EN/article/downloadArticleFile.do?attachType=PDF&id=9577
Abstract: In this paper, the preparation and properties of chiral monolithic stationary phases for liquid chromatography are reported. The preparation of molecularly imprinted monolithic stationary phases is very simple as bulk polymerization and suspension polymerization are not required. Most enantiomers of amino acid derivatives can be successfully resolved on the corresponding molecularly imprinted monolithic stationary phase. The selectivity on the monoliths is found to be mostly dependent on the structures of the template molecules. Thermodynamic investigations further demonstrate that the matching between analytes and recognition cavity plays a very important role in the recognition process of a molecularly imprinted polymer. (Analytical Abstracts 2004)
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