Paper 2661

Home
Papers
- Papers 2021 onwards
  - in press
  - 2022
  - 2021
- Papers 2011 onwards
  - 2020
  - 2019
  - 2018
  - 2017
  - 2016
  - 2015
  - 2014
  - 2013
  - 2012
  - 2011
- Papers 2001-2010
  - 2010
  - 2009
  - 2008
  - 2007
  - 2006
  - 2005
  - 2004
  - 2003
  - 2002
  - 2001
- Papers 1991-2000
  - 2000
  - 1999
  - 1998
  - 1997
  - 1996
  - 1995
  - 1994
  - 1993
  - 1992
  - 1991
- Papers 1930s-1990
  - 1990
  - 1989
  - 1980s
  - 1970s
  - 1960s
  - 1950s
  - 1940s
  - 1930s
- Journals
  - Journals A-I
    - A
    - B
    - C
    - D
    - E
    - F
    - G
    - H
    - I
  - Journals J-R
    - J
    - K
    - L
    - M
    - N
    - O
    - P
    - Q
    - R
  - Journals S-Z
    - S
    - T
    - U
    - V
    - W
    - X
    - Y
    - Z
  - Journal Rankings
  - Papers by year
- Theses & dissertations
Authors
- Authors A-I
  - A
  - B
  - C
  - D
  - E
  - F
  - G
  - H
  - I
- Authors J-R
  - J
  - K
  - L
  - M
  - N
  - O
  - P
  - Q
  - R
- Authors S-Z
  - S
  - T
  - U
  - V
  - W
  - X
  - Y
  - Z
- Author Stats
Keywords
- Keywords A-I
  - A
  - B
  - C
  - D
  - E
  - F
  - G
  - H
  - I
- Keywords J-R
  - J
  - K
  - L
  - M
  - N
  - O
  - P
  - Q
  - R
- Keywords S-Z
  - S
  - T
  - U
  - V
  - W
  - X
  - Y
  - Z
- Templates A-I
  - A
  - B
  - C
  - D
  - E
  - F
  - G
  - H
  - I
- Templates J-R
  - J
  - K
  - L
  - M
  - N
  - O
  - P
  - Q
  - R
- Templates S-Z
  - S
  - T
  - U
  - V
  - W
  - X
  - Y
  - Z
Patents
- Patents 2011 onwards
  - 2018
  - 2017
  - 2016
  - 2015
  - 2014
  - 2013
  - 2012
  - 2011
- Patents 2001-2010
  - 2010
  - 2009
  - 2008
  - 2007
  - 2006
  - 2005
  - 2004
  - 2003
  - 2002
  - 2001
- Patents 1991-2000
  - 2000
  - 1999
  - 1998
  - 1997
  - 1996
  - 1995
  - 1994
  - 1993
  - 1992
  - 1991
- Patents 1960s-1989
  - 1989
  - 1986
  - 1970s
  - 1960s
- Patents by year
Inventors
- Inventors A-I
  - A
  - B
  - C
  - D
  - E
  - F
  - G
  - H
  - I
- Inventors J-R
  - J
  - K
  - L
  - M
  - N
  - O
  - P
  - Q
  - R
- Inventors S-Z
  - S
  - T
  - U
  - V
  - W
  - X
  - Y
  - Z
- Inventor Stats
Resources
Search
Contact

Custom Search

Reference type: Journal
Authors: Clavier CW, Rodman DL, Sinski JF, Allain LR, Im HJ, Yang Y, Clark JC, Xue ZL
Article Title: A method for the preparation of transparent mesoporous silica sol-gel monoliths containing grafted organic functional groups.
Publication date: 2005
Journal: Journal of Materials Chemistry
Volume: 15
Issue: (24)
Page numbers: 2356-2361.
DOI: 10.1039/b417014h

Abstract: Transparent, crack-free mesoporous silica sol-gel monolith 2 was prepared from the hydrolysis of Si(OMe)(4) in MeOH containing ethylene glycol (HOCH2CH2OH). Gradual exposure of the product monolith 1 to MeOH/H2O and then H2O helps prevent cracking of the monolith. Direct reaction of chelating diamine H2N(CH2)(2)NH(CH2)(3)Si(OMe)(3) with 1 gave diamine-grafted monolith 3. Imprint-grafting of monolith 1 with the Cu2+ complex Cu[H2N(CH2)(3)Si(OMe)(3)](4)(2+) yielded monolith 5 grafted with the monoamine ligand H2N(CH2)(3)Si(O-)(3) (APS). BET studies showed that the average pore size in amine-imprint- grafted 5 was ca. 47 angstrom with a specific surface area of 232 m(2) g(-1), and the total pore volume was 0.24 cm(3) g(-1) for all pores of the gel which were less than 174 angstrom
Template and target information: Cu[H2N(CH2)(3)Si(OMe)(3)](4)(2+)

Join the Society for Molecular Imprinting

New items RSS feed

View latest updates

Sign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent e-mail alerts.
Click here to go to the sign-up page.

Is your name elemental or peptidic? Enter your name and find out by clicking either of the buttons below!

NAMES spelled in amino acids as a peptide

Other products you may like:

view listings for MIP books on eBay: