MIPs logo MIPdatabase      MIP2024 Conference banner, website is now open, register on site for important updates   
Custom Search
Reference type: Journal
Authors: Chailapakul O, Crooks RM
Article Title: Synthesis and characterization of simple self-assembling, nanoporous monolayer assemblies - A new strategy for molecular recognition.
Publication date: 1993
Journal: Langmuir
Volume: 9
Issue: (4)
Page numbers: 884-888.
DOI: 10.1021/la00028a002

Abstract: Composite monolayer films spontaneously adsorb onto the surface of Au from an ethanolic mixture of two mercaptans to form a nanoporous surface. The monolayers consist of an electron- transfer-retarding n-alkanethiol framework, which passivates the Au surface, and a much shorter aromatic mercaptan, which induces molecular-sized defects within the passivating framework. Electrochemical experiments indicate that the chemical nature of the template and the template/framework ratio in the deposition solution control the size, number, and chemical characteristics of the defects. For example, 4- hydroxythiophenol/1-hexadecanethiol mixed monolayers yield monolayer assemblies that admit Ru(NH3)63+ probe molecules but not Fe(CN)63-

  Mister Benzene shirt  Mug featuring the name Richard spelled out in the single letter amino acid code  Beach bunny periodic table shirt


Join the Society for Molecular Imprinting
Logo of the Society for Molecular Imprinting

New items RSS feed
new items RSS feed  View latest updates

Sign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent e-mail alerts.
Click here to go to the sign-up page.

Is your name elemental or peptidic? Enter your name and find out by clicking either of the buttons below!
Other products you may like:
view listings for MIP books on eBay:

Mickey Mouse 90th Anniversary banner