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Reference type: Journal
Authors: Kubo T, Hosoya K, Sano T, Nomachi M, Tanaka N, Kaya K
Article Title: Selective separation of brominated bisphenol A homologues using a polymer-based medium prepared by the fragment imprinting technique.
Publication date: 2005
Journal: Analytica Chimica Acta
Volume: 549
Issue: (1-2)
Page numbers: 45-50.
DOI: 10.1016/j.aca.2005.06.015
Alternative URL: http://www.sciencedirect.com/science/article/B6TF4-4GMS9D9-3/2/ead6077e0cdf24516691e371f719b5fd

Abstract: To achieve the selective separation of brominated aromatic compounds, the polymer-based separation media were prepared by the fragment imprinting technique and were evaluated with high-performance liquid chromatography. In the results, the separation medium prepared with 2,6-bis-(trifluoromethyl)-benzoic acid as the template showed the selective retention abilities for 3,5- and/or 3',5'-brominated or chlorinated bisphenol A homologues. The selective retention seems due to the shape recognition according to the alternative template molecule. Especially, the tetrabromo- or tetrachloro-bisphenol A homologues were selectively recognized by the imprinting effect
Template and target information: 2,6-bis-(trifluoromethyl)-benzoic acid, tetrachlorobisphenol A, tetrabromobisphenol A
Author keywords: fragment imprinting, Selective retention, Brominated or chlorinated bisphenol A, Alternative template molecules


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