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Reference type: Conference Proceeding
Authors: Yamashita K, Kondo F, Nishimura T, Ohashi K, Dewa T, Nango M
Publication date: 2002
Article title: Attempts to imprinting of hydrogel in aqueous system.
Page numbers: 684
Alternative URL: http://www.jstage.jst.go.jp/article/spsjppj/51m/0/51m_684/_article

Proceedings title: Polymer Preprints, Japan
Volume number: 51m

Abstract: We aimed to design the imprinting hydrogel that recognize a substrate in aqueous environment where a hydrogen bond does not work for the recognition. We used a metal-ligand coordination interaction to recognize the substrate in aqueous environment. We prepared imprinted hydrogel adsorbents, poly(sodium acrylate) (PNaAAc)-PNIPAm copolymers, whose binding ability and metal ion selectivity can be controlled by external stimuli. In this study, we report the two-step preparation method of the stimuli-responsive imprinting hydrogel and its application to the adsorbing system for heavy metal ions. We first controlled the recognition ability of the imprinted hydrogel-adsorbent by using the external thermal stimuli.


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