MIPdatabase
Authors: Kim KS, Lee JH, Kim MH, Cho SH
Article Title: Preparation and characterization of molecularly imprinted uniform-sized Poly(4VP-co-EGDMA) microgels.
Publication date: 2005
Journal: Polymer Journal
Volume: 37
Issue: (9)
Page numbers: 669-676.
DOI: 10.1295/polymj.37.669
Alternative URL: http://www.jstage.jst.go.jp/article/polymj/37/9/37_669/_article
Abstract: Molecularly imprinted uniform-sized poly(4VP-co-EGDMA) microgels were prepared from 4-vinyl pyridine (4VP) monomer and ethylene glycol dimethacrylate (EGDMA) as crosslinking agent using monodisperse linear polystyrene seed particles by multi-step swelling polymerization method.The polymerization conditions were chosen in such a way that the formation of solution complexes between 4VP and the template (N-protected amino acid) prior to polymerization would be favored. The effects of polymerization parameters such as weight ratio of the monomer/seed and diluent/monomer, the concentration of crosslinking agent on the average particle size and pore size distribution were investigated.The molecularly imprinted polymer microgels were utilized as a stationary phase in HPLC. In the chromatographic mode, resolution of the enantiomers of Cbz-L,D-aspartic acid (Cbz: carbobenzoxy) were resolved with the imprinted polymer
Template and target information: Cbz-aspartic acid
Author keywords: polymer microgel, molecularly imprinted polymer, seed polymerization, monodisperse polymer particle
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