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Reference type: Conference Proceeding
Authors: Kuzmic AE, Vukovic R, Bogdanic G, Fles D
Publication date: 2004
Article title: Molecularly imprinted crosslinked copolymers prepared by thermal degradation of poly(N-methacryl-N,N'-dicyclohexylurea-co-ethylene glycol dimethacrylate).
Page numbers: 2679-2685

ISBN: 8086059405
Conference information: CHISA 2004 - 16th International Congress of Chemical and Process Engineering

Abstract: The preparation of nanoporous copolymers of poly(N-methacryl-N-cyclohexylamide-co-ethylene glycol dimethacrylate), poly(MA-CHA-co-EDMA), by thermal degradation of poly (N-methacryl-N,N'-dicyclohexylurea-co-ethylene glycol dimethacrylate), poly(MA-DCU-co-EDMA) were studied. MA-DCU was copolymerized with EDMA to a high conversion under the formation crosslinked copolymers. In the thermogravimetric analysis, copolymers decomposed by a two-step mechanism under the separation of almost quantitative yield of c6H11NCO at temperature of 250�C. After removal of cyclohexylisocyanate from the crosslinked copolymers, recognition groups-CO-NHC6H11 remain as reactive sites in nanoporous copolymers

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