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Reference type: Journal
Authors: Fujii Y, Kikuchi K, Matsutani K, Ota K, Adachi M, Syoji M, Haneishi I, Kuwana Y
Article Title: Template synthesis of polymer schiff-base cobalt(III) Complex and formation of specific cavity for chiral amino-acid.
Publication date: 1984
Journal: Chemistry Letters
Volume: 13
Issue: (9)
Page numbers: 1487-1490.
DOI: 10.1246/cl.1984.1487

Abstract: Template synthesis for D-2-[Co(Schiff base)(D-phe)] (Schiff base = 4-(p-vinylbenzyloxy)-sal2-(R,R)-chxn) was carried out by copolymerizing the complex with styrene and divinylbenzene. After treating the formed polymer complex gel with HCl, the gel took in D-phe preferentially (maximum optical purity = 74%), when it reacted with an excess of DL-PHE.
Template and target information: D-Phe, D-phenylalanine


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