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Reference type: Journal
Authors: Matsui J, Ochi Y, Tamaki K
Article Title: Photodimerization of anthryl moieties in a poly(methacrylic acid) derivative as reversible cross-linking step in molecular imprinting.
Publication date: 2006
Journal: Chemistry Letters
Volume: 35
Issue: (1)
Page numbers: 80-81.
DOI: 10.1246/cl.2006.80
Alternative URL: http://www.jstage.jst.go.jp/article/cl/35/1/35_80/_article

Abstract: A methodology for reversible molecular imprinting is presented. A molecularly imprinted polymer (MIP) is prepared by photo-cross-linking poly(methacrylic acid) (PMAA) with anthryl moieties as photo-cross-linking sites in the presence of an antimalarial drug cinchonidine as a template molecule, resulting in enhanced binding capacity to cinchonidine, compared with non-imprinted polymers. MIP is then "initialized" by exposure to shortwave UV that cleaves the anthracene-dimer-based cross-links, resulting in the reduced binding capacity comparable to the non-imprinted polymers.
Template and target information: cinchonidine


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