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Reference type: Journal
Authors: Park JK, Lee JW
Article Title: Characteristics of selective adsorption using D-Phenylalanine imprinted terpolymer beads.
Publication date: 2005
Journal: Korean Journal of Chemical Engineering
Volume: 22
Issue: (6)
Page numbers: 927-931.
DOI: 10.1007/BF02705677
Alternative URL: http://www.cheric.org/PDF/KJChE/KC22/KC22-6-0927.pdf

Abstract: A D-Phenylalanine (Phe) imprinted terpolymer, Polyacrylonitrile-Poly(acrylic acid)-Poly(acryl amide) (Poly(AN-AA-AAm)) bead was prepared by the wet-phase inversion method. Acrylamide (AAm) and acrylic acid (AA) were used as the functional monomer and acrylonitrile (AN) was used as a physical cross linker. The characteristics of selective adsorption by the D-Phe imprinted terpolymer beads were investigated at high concentrations of Phe racemate solution, 1 g Phe/L, and 10 g Phe/L. The adsorption selectivity of the D-Phe imprinted terpolymer beads prepared by an in-situ implanting method reached 0.82 and 0.8 at 1.0 g and 10 g Phe/L racemate solution, respectively, and almost all of the adsorbed D-Phe and about 43% of the adsorbed L-Phe were desorbed by 4% acetic acid. The uptake capacities of the terpolymer beads were maintained for several repeated batches
Template and target information: D-Phenylalanine, Phe, D-Phe
Author keywords: molecularly imprinted polymer, phenylalanine, bead, wet-phase inversion method, repeated batch


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