MIPdatabase
Authors: Vukovic R, Kuzmic AE, Bogdanic G, Fles D
Publication date: 2005
Chapter title: Preparation of molecularly imprinted cross-linked copolymers by thermal degradation of poly(methacryl-N,N '-diisopropylurea-co-ethylene glycol dimethacrylate).
Chapter number: 17
Page numbers: 229-237.
DOI: 10.1021/bk-2005-0916.ch017
Book title: New Polymeric Materials
Editors: Korugic-Karasz LS, MacKnight WJ, Martuscelli E
Publisher: The American Chemical Society
City: Washington DC
Series title: ACS Symposium Series
Volume number: 916
Abstract: Crosslinked porous copolymers of methacryl-isopropylamide with ethylene glycol dimethacrylate, poly(MA-WrA-co-EDMA), were prepared by thermal degradation of crosslinked copolymers of methacryl-diisopropylurea with ethylene glycol dimethacrylate, poly(MA-DiPrU-co-EDMA), at temperature of 180-250 degrees C in vacuum or under TGA conditions in nitrogen. Nonporous copolymers which represent the model compound of porous copolymers of the same structure were also prepared. Both, porous and nonporous model copolymers have almost the same thermal stability as shown by TGA measurements. At the same time the T. of porous and nonporous model copolymers are different and indicate that nonporous copolymers have higher structural ordering
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