MIPs logo MIPdatabase      MIP2020 Conference logo Use this space
Custom Search
Reference type: Journal
Authors: Kuzmic AE, Vukovic R, Bogdanic G, Fies D
Article Title: The influence of the chemical structure on the properties of molecularly imprinted crosslinked polymers [Utjecaj kemijske strukture na svojstva molekulski tiskanih umreženih polimera].
Publication date: 2006
Journal: Polimeri (Zagreb)
Volume: 26
Issue: (4)
Page numbers: 176-182.
Alternative URL: http://hrcak.srce.hr/index.php?show=clanak&id_clanak_jezik=5263

Abstract: The present paper describes the synthesis of monomers N-methacryl-N, N'-dicyclohexylurea (MA-DCU) and N-methacryl-N,N'-diisopropylurea (MA-DiPrU) and their polymerization with ethylene glycol dimethacrylate (EDMA). Polymerization were carried out in butanone by using dibenzoyl-peroxide (Bz 2O2) up to high conversion. All prepared copolymers are insoluble in common organic solvent. Crosslinked copolymers decompose thermally at temperatures from 180 °C to 450 °C under the separation of cyclohexylisocyanate (C6H11NCO) or isopropylisocyanate (C3H7NCO) at temperature between 180 °C and 250 °C. Residues after the removal of isocyanate are thermally stable nanoporous crosslinked copolymers of methacryl-cyclohexylamide (MA-CHA) or methacryl-isopropylamide (MA-iPrA) with EDMA, which decompose by a one-step mechanism between 280 °C and 450 °C. Nonporous model copolymers of MA-CHA and MA-iPrA with EDMA were also prepared in order to compare their properties with the properties of corresponding nanoporous copolymers
Author keywords: Chemical structure, Molecularly imprinted copolymers,imprinted copolymers, Nanoporous copolymers,nonporous copolymers, Poly(N-methacryl-N,N'- dicyclohexylurea-co-ethylene-glycol dimethacrylate), poly(N-methacryl-N,N'-diisopropylurea-co-ethylene-glycol


  Mister Benzene shirt  Chemistry peptide mug  Beach bunny periodic table shirt

Molecules Special Issue call      Appeal for information






 

Join the Society for Molecular Imprinting
Logo of the Society for Molecular Imprinting

New items RSS feed
new items RSS feed  View latest updates

Sign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent e-mail alerts.
Click here to go to the sign-up page.


Is your name elemental or peptidic? Enter your name and find out by clicking either of the buttons below!
Other products you may like:
view listings for MIP books on eBay:



Mickey Mouse 90th Anniversary banner