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Reference type: Journal
Authors: Yoshikawa M, Murakoshi K, Kogita T, Hanaoka K, Guiver MD, Robertson GP
Article Title: Chiral separation membranes from modified polysulfone having myrtenal-derived terpenoid side groups.
Publication date: 2006
Journal: European Polymer Journal
Volume: 42
Issue: (10)
Page numbers: 2532-2539.
Alternative URL: http://www.sciencedirect.com/science/article/B6TWW-4K66F5H-1/2/b2772bec9c41813b797959d1419b4182

Abstract: Novel polymeric materials, having a chiral environment, were obtained by the reaction of lithiated polysulfone with chiral terpenoid myrtenal. The resulting polymers gave self-standing durable membranes. Molecularly imprinted membranes were prepared from the novel myrtenal-containing polysulfones by the presence of print molecules during the membrane preparation process. The d-isomer imprinted membrane showed d-isomer adsorption and diffusivity selectivity, and vice versa. As a result, the d-isomer imprinted membrane transported the d-isomer in preference to the l-isomer, and vice versa. The control non-imprinted membrane also showed permselectivity toward racemic glutamic acid mixtures. The expression of permselectivity for the molecularly imprinted membranes was synergistically due to adsorption and diffusivity selectivity
Template and target information: glutamic acid
Author keywords: chiral separation, membrane, molecular imprinting, Myrtenal, optical resolution, polysulfone, permselectivity, adsorption selectivity, Diffusivity selectivity


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