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Reference type: Conference Proceeding
Authors: Hall AJ, Manesiotis P, Mossing JT, Sellergren B
Publication date: 2002
Article title: Molecularly imprinted polymers (MIPs) against uracils: Functional monomer design, monomer-template interactions in solution and MIP performance in chromatography.
Page numbers: 11-15
DOI: 10.1557/PROC-723-M1.3 Alternative URL: http://www.dtic.mil/cgi-bin/GetTRDoc?AD=ADA412559&Location=U2&doc=GetTRDoc.pdf

Editors: Shea KJ, Yan M, Roberts MJ, Cremer PS, Crooks RM, Sailor MJ
Publisher: Materials Research Society
Volume number: 723
Conference information: Molecularly Imprinted Materials-Sensors And Other Devices

Abstract: The interaction of N-1-substituted uracils (cyclohexyl (1) and benzyl (2)) with three polymerisable recognition elements, the novel monomers 9-(3/4-vinylbenzyl)adenine (3) and 2,6-diamino- 9-(3/4-vinylbenzyl)purine (4) and the previously synthesised monomer 2,6bis(acrylamido)pyridine (5), has been studied via H- 1 NMR in deuterio-chloroform solution. MIPs against (2) have been prepared using each of the monomers and tested in the chromatographic mode. The effect of the number and type of hydrogen bonds formed between the templates and the functional monomers is reflected in the values of the apparent association constants obtained from the solution study and by the performance of the subsequently prepared MIPs in the chromatographic mode


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