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Reference type: Journal
Authors: Wang S, Xu Z, Fang G, Duan Z, Zhang Y, Chen S
Article Title: Synthesis and Characterization of a Molecularly Imprinted Silica Gel Sorbent for the On-Line Determination of Trace Sudan I in Chilli Powder through High-Performance Liquid Chromatography.
Publication date: 2007
Journal: Journal of Agricultural and Food Chemistry
Volume: 55
Issue: (10)
Page numbers: 3869-3876.
DOI: 10.1021/jf070261t

Abstract: Abstract: A highly selective imprinted polymer was synthesized by a surface molecular imprinting technique in combination with a sol-gel process. The imprinted polymer was evaluated by FT-IR and static and kinetic adsorption experiments. The results showed that the imprinted sorbent exhibited good recognition and selective ability, offered a faster kinetics for the adsorption and desorption of Sudan I than the non-imprinted sorbent, a saturated binding capacity (Qmax) that reached 33.47 mg g-1. The prepared sorbent was applied for the determination of trace Sudan I through on-line solid-phase coupled with high-performance liquid chromatography (SPE-HPLC). With a loading flow rate of 1.5 mL min-1 for sampling 50 mL, an enrichment factor of 1266 was achieved. The detection limit (S/N = 3) was 1.2 ng L-1, and the peak area precision (RSD) for five replicate detections of 0.01 g L-1 Sudan I was 3.66%. The Sudan I in the chilli powder from the local market was determined at three levels (0.25, 0.5, and 1.0 ng g-1) with recoveries ranging from 80.31 to 94.02%. Keywords: Sudan I; molecular imprinting; sol-gel; on-line solid-phase extraction; high-performance liquid chromatography
Template and target information: Sudan I
Author keywords: Sudan I, molecular imprinting, sol-gel, On-line solid phase extraction, high-performance liquid chromatography


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