Reference type: Journal
Authors: Gomy C,
Schmitzer AR
Article Title: Synthesis and Photoresponsive Properties of a Molecularly Imprinted Polymer.
Publication date: 2007
Journal: Organic Letters
Volume: 9
Issue: (20)
Page numbers: 3865-3868.
DOI: 10.1021/ol701618n
Abstract: Abstract: A photoresponsive molecularly imprinted polymer was prepared from a di(ureidoethylenemethacrylate)azobenzene monomer, using a methotrexate analogue as template. Photoisomerization of the 3D crosslinked polymer matrix allowed switching the substrate affinity by altering the geometry and spatial arrangement of the receptor binding sites. As a result, controlled release and uptake of the template (or analogous ligands) were obtained
Template and target information: bis(TBA)-N-Z-L-glutamate
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