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Reference type: Journal
Authors: Guan GJ, Zhang ZP, Wang ZY, Liu BH, Gao DM, Xie CG
Article Title: Single-Hole Hollow Polymer Microspheres toward Specific High-Capacity Uptake of Target Species.
Publication date: 2007
Journal: Advanced Materials
Volume: 19
Issue: (17)
Page numbers: 2370-2374.
DOI: 10.1002/adma.200700984

Abstract: The preparation of single hole hollow microsphere of poly(AA-EGDMA) through the direct polymerization and cross linking reactions occurring at the surface of carboxyl capping polystyrene colloids was reported. The carboxyl-capping PS beads with a uniform size of 400 nm were synthesized using an emulsifier-free copolymerization. Acrylamide (AA) and ethylene glycol dimethacrylate (EGDMA) were used as the functional monomer and crosslinking agent for the shell materials. The results indicated that core-shell microspheres without holes are obtained if a one-step polymerization at 60C was used. The approach allows imprinting of various organic biological molecular at the single-hole hollow polymer microspheres towards the molecular recognition and high capacity uptake of target species
Template and target information: TNT, 2,4,6-trinitrotoluene
Author keywords: Core, shell particles, hollow spheres, microspheres, Polystyrene (PS), template-directed synthesis


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