Book title: Handbook of Heterogeneous Catalysis
Editors: Ertl G, Knözinger H, Schüth F, Weitkamp J
Publisher: Wiley
Abstract: The sections in this article are
1 Introduction and Scope
2 Metal Complex–Support Interaction
3 Physically Immobilized ("Entrapped") Metal Complexes
3.1 Intrazeolite Assembly: Ship-in-a-Bottle Catalysts
3.2 Entrapment in Sol–Gel and Polysiloxane Matrices
3.3 Microencapsulation and Polymer-Incarcerated Methods
3.4 Supramolecular Complexation: Mechanical Immobilization
4 Tethered Metal Complexes
4.1 Multifunctional Surfaces
4.2 Spatial Restrictions Imparted by Periodic Mesoporous Silica
4.3 Site Isolation via Spatial Patterning of the Silica Surface
5 Grafted Metal Complexes: Surface Organometallic Chemistry (SOMC)
5.1 Alkyl-Based SOMC
5.2 Alkoxide-Based SOMC
5.3 Amide-Based SOMC
5.4 Molecular Model Oxo–Surfaces
6 Metal–Organic Assemblies: Self-Immobilized Homogeneous Catalysts
6.1 Metal–Organic Frameworks
6.1.1 Achiral Metal–Organic Assemblies
6.1.2 Chiral Metal–Organic Assemblies
6.2 Matrix-Embedded Catalysts
6.2.1 Sol–Gel-Processed Interphase Catalysts
6.2.2 Organic–Polymer-Embedded Catalysts
6.2.3 Self-Immobilizing Polymerization Catalysts
6.2.4 Molecularly Imprinted Polymers
6.3 Liquid Crystal Assemblies
Keywords: immobilization; anchored catalysts; supported catalysts; hybrid catalysts
Template and target information: Review - immobilized molecular catalysts