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Reference type: Book Chapter
Authors: Anwander R
Publication date: 2008
Chapter title: Immobilization of Molecular Catalysts.
Chapter number: 2.4.9
Page numbers: 583-614.
DOI: 10.1002/9783527610044.hetcat0029

Book title: Handbook of Heterogeneous Catalysis
Editors: Ertl G, Knözinger H, Schüth F, Weitkamp J
Publisher: Wiley

Abstract: The sections in this article are 1 Introduction and Scope 2 Metal Complex–Support Interaction 3 Physically Immobilized ("Entrapped") Metal Complexes 3.1 Intrazeolite Assembly: Ship-in-a-Bottle Catalysts 3.2 Entrapment in Sol–Gel and Polysiloxane Matrices 3.3 Microencapsulation and Polymer-Incarcerated Methods 3.4 Supramolecular Complexation: Mechanical Immobilization 4 Tethered Metal Complexes 4.1 Multifunctional Surfaces 4.2 Spatial Restrictions Imparted by Periodic Mesoporous Silica 4.3 Site Isolation via Spatial Patterning of the Silica Surface 5 Grafted Metal Complexes: Surface Organometallic Chemistry (SOMC) 5.1 Alkyl-Based SOMC 5.2 Alkoxide-Based SOMC 5.3 Amide-Based SOMC 5.4 Molecular Model Oxo–Surfaces 6 Metal–Organic Assemblies: Self-Immobilized Homogeneous Catalysts 6.1 Metal–Organic Frameworks 6.1.1 Achiral Metal–Organic Assemblies 6.1.2 Chiral Metal–Organic Assemblies 6.2 Matrix-Embedded Catalysts 6.2.1 Sol–Gel-Processed Interphase Catalysts 6.2.2 Organic–Polymer-Embedded Catalysts 6.2.3 Self-Immobilizing Polymerization Catalysts 6.2.4 Molecularly Imprinted Polymers 6.3 Liquid Crystal Assemblies Keywords: immobilization; anchored catalysts; supported catalysts; hybrid catalysts
Template and target information: Review - immobilized molecular catalysts


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