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Reference type: Journal
Authors: Li SJ, Gong SQ
Article Title: A Substrate-Selective Nanoreactor Made of Molecularly Imprinted Polymer Containing Catalytic Silver Nanoparticles.
Publication date: 2009
Journal: Advanced Functional Materials
Volume: 19
Issue: (16)
Page numbers: 2601-2606.
DOI: 10.1002/adfm.200900428

Abstract: An original, substrate-selective nanoreactor is designed and characterized. The nanoreactor made of a 4-nitrophonel (NP)-imprinted polymer and Ag nanoparticles, can specifically recognize NP compared with its analogues 4-nitrophenyl acetate (NPA) and 2,6-dimethyl-4-nitrophenol (DNP). Under comparable conditions, this nanoreactor significantly accelerated the reduction of NP; however, much less acceleration is shown for its analogues. Unlike traditional Ag nanoreactors, which lack molecular recognition abilities, this unique nanoreactor is composed of molecularly imprinted networks, making substrate-selective catalysis feasible
Template and target information: 4-nitrophenol, 4-NP
Author keywords: catalysis, Metal nanoparticles, molecular imprinting, molecular recognition


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