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Reference type: Journal
Authors: Xu ZX, Fang GZ, Wang S
Article Title: Molecularly imprinted solid phase extraction coupled to high-performance liquid chromatography for determination of trace dichlorvos residues in vegetables.
Publication date: 2010
Journal: Food Chemistry
Volume: 119
Issue: (2)
Page numbers: 845-850.
DOI: 10.1016/j.foodchem.2009.08.047
Alternative URL: http://www.sciencedirect.com/science/article/B6T6R-4X5JR9S-B/2/e0b61c1aeca0c4243ac9e0a6e76da2cc

Abstract: In this paper, we prepared a highly selective imprinted polymer by a room temperature ionic liquid-mediated bulk polymerization technique, using dichlorvos as the template, methacrylic acid as the functional monomers, and trimethylolpropane trimethacrylate as the cross-linker. This functionalized material was characterized by FT-IR, static and kinetic adsorption experiments, and the results showed that this imprinted sorbent exhibited good recognition and selective ability, and offered fast kinetics for the adsorption and desorption of dichlorvos. Using the prepared material as a solid phase extraction sorbent, a novel sample pre-treatment technique that can be coupled to high-performance liquid chromatography (HPLC) had been developed for determination of trace dichlorvos residues in foods. Under the selected experimental condition, the detection limit (S/Ná=á3) of dichlorvos was 94.8ángáL-1, and the peak area precision (RSD) for five replicate detections of 10áμgáL-1 dichlorvos was 4.41%. The blank samples of cucumber and lettuce spiked with dichlorvos at 0.005 and 0.02áμgág-1 levels were determined with recoveries ranging from 82.1% to 94.0%
Template and target information: dichlorvos
Author keywords: Dichlorvos, molecular imprinting, solid phase extraction, high-performance liquid chromatography


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