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Reference type: Journal
Authors: Ates Z, Gven O
Article Title: Radiation-induced molecular imprinting of d-glucose onto poly(2-hydroxyethyl methacrylate) matrices using various crosslinking agents.
Publication date: 2010
Journal: Radiation Physics and Chemistry
Volume: 79
Issue: (3)
Page numbers: 219-222.
DOI: 10.1016/j.radphyschem.2009.10.010
Alternative URL: http://www.sciencedirect.com/science/article/B6TVT-4XMD5GF-1/2/e7e87a373a5437fc6a43088c0d203d50

Abstract: Radiation-induced molecular imprinting of d-glucose onto poly(2-hydroxyethyl methacrylate) matrix was achieved to create three-dimensional cavities to recognize and bind d-glucose. The optimization of imprinting capability of matrices was achieved by investigating the effects of various parameters such as the type and amount of crosslinking agent, type of solvent, template to monomer ratio and total absorbed dose. Crosslinking agents with increasing chain lengths and different flexibilities were used in an attempt to elucidate the impact of relevant imprint parameters on the effectiveness of imprinting technique. The absorbed dose varied from 1 to 15kGy. Cavity sizes of MIPs were measured by positron annihilation lifetime (PAL) experiments. Control matrices were synthesized with exactly the same composition in the absence of d-glucose. Separation of d-glucose has been shown to be successfully achieved in HPLC columns filled with MIPs whereas no separation was observed for non-imprint matrices
Template and target information: d-glucose, monosaccharide, glucose
Author keywords: Positron annihilation lifetime (PAL) spectroscopy, molecular imprinting, Free volume, d-Glucose, 2-Hydroxyethyl methacrylate (HEMA)


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