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Reference type: Journal
Authors: Zhang J, Wang YQ, Lv RH, Xu L
Article Title: Electrochemical tolazoline sensor based on gold nanoparticles and imprinted poly-o-aminothiophenol film.
Publication date: 2010
Journal: Electrochimica Acta
Volume: 55
Issue: (12)
Page numbers: 4039-4044.
DOI: 10.1016/j.electacta.2010.02.021
Alternative URL: http://www.sciencedirect.com/science/article/B6TG0-4YFTM56-1/2/38e86dcf48128563dd739b81defe5297

Abstract: Amperometric detection of tolazoline (TL) was carried out on a gold nanoparticles (AuNPs)/poly-o-aminothiophenol (PoAT)-modified electrode by a molecular imprinting technique and electropolymerization method. The modification procedure was characterized via electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). The recognition between the imprinted sensor and target molecule was observed by measuring the variation of amperometric response of the oxidation-reduction probe, K3Fe(CN)6 on electrode. Under the optimal experimental conditions, the peak currents were proportional to the concentrations of tolazoline in two ranges of 0.05-5.0áμgámL-1 and 5.0-240áμgámL-1 with the detection limit of 0.016áμgámL-1. Meanwhile the prepared sensor showed sensitive and selective binding sites for tolazoline. The enhancement of sensitivity was attributed to the presence of AuNPs which decreased the electron-transfer impedance
Template and target information: tolazoline, TL
Author keywords: Molecularly imprinted polymer films, amperometric sensor, gold nanoparticles, tolazoline, o-aminothiophenol


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