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Reference type: Journal
Authors: Zhou J, He XW, Shi HM
Article Title: Study on the characteristics of molecular recognition of metal-complexing template polymers.
Publication date: 1999
Journal: Journal of Analytical Science
Volume: 15
Issue: (2)
Page numbers: 89-93.
Alternative URL: http://en.cnki.com.cn/Article_en/CJFDTotal-FXKX902.000.htm

Abstract: The cited polymer, which has binding sites analogous to metal-chelate antibody, was synthesized by molecular imprinting technique with the Co(II)-diphenadione (diphacinone; I) complex as template, 4-vinylpyridine as functional monomer and ethylene glycol dimethacrylate as crosslinking monomer. Its characteristics of molecular recognition were studied by spectrophotometry (details given) and equilibrium binding experiments showed that the selective recognition of I by the polymer was markedly enhanced at the optimum concentration of Co(II) acetate as compared with two control polymers with same composition. The recognition mechanism and binding selectivity of the polymer were discussed. (Analytical Abstracts 1999)
Template and target information: Co(II)-diphenadione complex


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