MIPs logo MIPdatabase      Use this space
Custom Search
Reference type: Journal
Authors: Huang WH, Zhou W, Xu WZ, Xu PP, Xu XJ, Yan YS
Article Title: Synthesis and Evaluation of Surface Molecular Imprinted Potassium Tetratitanate Whisker for Dibenzothiophene.
Publication date: 2011
Journal: Chinese Journal of Analytical Chemistry
Volume: 39
Issue: (4)
Page numbers: 560-563.
DOI: 10.3724/SP.J.1096.2011.00560
Alternative URL: http://en.cnki.com.cn/Article_en/CJFDTotal-FXHX201104030.htm

Abstract: A novel surface molecular imprinted material based on modification of potassium tetratitanate whisker has been successfully synthesized with dibenzothiophene(DBT) as template, 4-vinyl pyridine (4-VP) as functional monomer, potassium tetratitanate whisker (K2Ti4O9) as carrier. The synthetic sorbents were characterized by using the Fourier transform infrared spectroscopy, scanning electron microscopy and nitrogen adsorption. The adsorption conditions and properties of surface-imprinted/K2Ti4O9(MIP/K2Ti4O9) for selectivity of DBT were investigated. The experimental results showed that the optimum adsorption temperature was 318 K and adsorption time was 240 min. The equilibrium adsorption amount reached 23. 33 mg/g at an initial concentration of 500 mg/L; the adsorption process was described well with pseudo-second-order model, the chemisorption was dominant and the adsorption behavior was explained well with the Freundich isotherm equation, so it was a multi-molecular layer adsorption; the adsorption of DBT onto MIP/K2Ti4O9 was a spontaneous, endothermic and entropy-driven process. Selective adsorption test indicated that the MIP/K2Ti4O9 was a more effective sorbent than non-imprinted/K2Ti4O9(NIP/K2Ti4O9) toward DBT
Template and target information: dibenzothiophene, DBT
Author keywords: Surface-imprinted, dibenzothiophene, Potassium tetratitanate whisker, gas chromatography


  I love MIPs hat  multi MIPs logo mug  Irish periodic table patriotic shirt

Molecules Special Issue call      Appeal for information






 

Join the Society for Molecular Imprinting
Logo of the Society for Molecular Imprinting

New items RSS feed
new items RSS feed  View latest updates

Sign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent e-mail alerts.
Click here to go to the sign-up page.


Is your name elemental or peptidic? Enter your name and find out by clicking either of the buttons below!
Other products you may like:
view listings for MIP books on eBay:



Mickey Mouse 90th Anniversary banner