MIPdatabase
Authors: Wang SL, Dong XC, Wang N, Fan ZJ
Article Title: Synthesis and evaluation of the molecularly imprinted polymers for selective extraction of the mono-subsitituted sulfonylurea herbicides.
Publication date: 2007
Journal: Chinese Journal of Analysis Laboratory
Volume: 26
Issue: (10)
Page numbers: 88-92.
Alternative URL: http://en.cnki.com.cn/Article_en/CJFDTotal-FXSY200710025.htm
Abstract: New molecularly imprinted polymer(MIP) for selective extraction of NK#94827,a mono-subsitituted sulfonylurea herbicide,was synthesized with monosulfuron as the template and acrylamide as the functional monomer.The recognition property and affinity of the MIP for monosulfuron and its analog-NK#94827 were evaluated by equilibrium adsorption and chromatographic study.Recognition mechanism and influences of the mobile phase on the retention of the monosulfuron and NK#94827 were studied with resulting polymer as the stationary phase.The results showed that the MIP synthesized with acrylamide as the functional monomer has better selectivity for NK#94827 than the MIP synthesized with methacrylic acid.The MIP can be used as selective solid-phase extraction material for the sample cleanup in the determination of NK#94827 residue in soil.
Template and target information: NK#94827, sulfonylurea herbicide
Author keywords: molecularly imprinted polymer, Monosulfuron, NK#94827, Structural analog, selective extraction
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