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Reference type: Journal
Authors: Kamel AH, Moreira FTC, Silva TI, Sales MGF
Article Title: A Solid Binding Matrix/Mimic Receptor-Based Sensor System for Trace Level Determination of Iron Using Potential Measurements.
Publication date: 2011
Journal: International Journal of Electrochemistry
Volume: 2011
Page numbers: Article ID 643683.
DOI: 10.4061/2011/643683
Alternative URL: http://www.hindawi.com/journals/ijelc/2011/643683/

Abstract: Iron(II)-(1,10-phenanthroline) complex imprinted membrane was prepared by ionic imprinting technology. In the first step, Fe(II) established a coordination linkage with 1,10-phenanthroline and functional monomer 2-vinylpyridine (2-VP). Next, the complex was copolymerized with ethylene glycol dimethacrylate (EGDMA) as a crosslinker in the presence of benzoyl peroxide (BPO) as an initiator. Potentiometric chemical sensors were designed by dispersing the iron(II)-imprinted polymer particles in 2-nitrophenyloctyl ether (o-NPOE) plasticizer and then embedded in poly vinyl chloride (PVC) matrix. The sensors showed a Nernstian response for [Fe(phen)3]2+ with limit of detection 3.15 ng mL-1 and a Nernstian slope of 35.7 mV per decade.
Template and target information: Iron(II)-(1,10-phenanthroline) complex

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