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Reference type: Journal
Authors: Wu BW, Wang ZH, Xue ZH, Zhou XB, Du J, Liu XH, Lu XQ
Article Title: A novel molecularly imprinted electrochemiluminescence sensor for isoniazid detection.
Publication date: 2012
Journal: Analyst
Volume: 137
Issue: (16)
Page numbers: 3644-3652.
DOI: 10.1039/C2AN35499C

Abstract: Based on Ru(bpy)₃²⁺-Au nanoparticles decorated multi-walled carbon nanotubes composites and a molecularly imprinted polymer (MIP), we propose a novel molecularly imprinted electrochemiluminescence (ECL) sensor to selectively determine isoniazid (INH). The MIP is synthesized through electrochemical copolymerization of acrylamide and N,N'-methylene diacrylamide in the presence of INH template molecules. The enhanced ECL intensity is linear in the range of 0.1 to 110 μg cm-3 and the detection limit is 0.08 μg cm-3 (3σ) INH with relative standard deviation 3.8% (n = 6) for 8 μg cm-3. As a result, the sensor has been successfully applied to the determination of INH in human urine and pharmaceutical samples. Moreover, the possible ECL mechanism is discussed
Template and target information: isoniazid, INH

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