MIPdatabase
Authors: Hiratsuka Y, Funaya N, Matsunaga H, Haginaka J
Article Title: Preparation of magnetic molecularly imprinted polymers for bisphenol A and its analogues and their application to the assay of bisphenol A in river water.
Publication date: 2013
Journal: Journal of Pharmaceutical and Biomedical Analysis
Volume: 75
Page numbers: 180-185.
DOI: 10.1016/j.jpba.2012.11.030
Alternative URL: http://www.sciencedirect.com/science/article/pii/S0731708512006450
Abstract: Magnetic molecularly imprinted polymers (M-MIPs) for bisphenol A (BPA) and its structural analogues have been prepared by a multi-step swelling and polymerization method using uniformly-sized magnetic particles as a shape template. Binding experiments and Scatchard analyses revealed that two classes of binding sites were formed on M-MIPBPA. The retention and molecular-recognition properties of M-MIPs for BPA and its structural analogues were evaluated using a mixture of phosphate buffer and acetonitrile or a mixture of water and acetonitrile as a mobile phase by LC. M-MIPs for BPA and [2H16]BPA (BPA-d16), M-MIPBPA and M-MIPBPA-d16, showed almost the same imprinting factors for BPA, while M-MIP for bisphenol B (2,2-bis(4-hydroxyphenyl)butane, BPB), M-MIPBPB, gave the moderate imprinting factor for BPA. Furthermore, M-MIPBPB was applied for the selective extraction and determination of BPA in environmental water samples. The concentration of BPA in river water samples was determined to be 68 ng/L
Template and target information: bisphenol A, BPA
Author keywords: Magnetic molecularly imprinted polymer, sample preparation, environmental analysis, Bisphenols
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