Authors: Henschel H
, Klöckner JP
, Nicholls IA
, Prosenc MH
Computational and structural studies on the complexation of cobalt(II) acetate by water and pyridine.
Publication date: 2012
Journal: Journal of Molecular Structure
Alternative URL: http://www.sciencedirect.com/science/article/pii/S0022286011007770
Abstract: Four different complexes of the cobalt(II) acetate-pyridine-water system were obtained as dominant species by crystallization from a series of dichloromethane and toluene solutions. The complexes were characterized by terms of X-ray crystal structure determination. Factors in solution properties leading to crystallization of certain complexes are discussed. Furthermore, trends in terms of structure and binding energies in a systematic series of mononuclear cobalt(II) complexes were studied using density functional calculations
Author keywords: cobalt, coordination, crystal structure, Density functional calculation
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