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Abstract: An ion imprinted polymer (IIP) based on aniline-formaldehyde was synthesized and then modified with extra aniline as cross-linker in the presence and absence of Sr (II) as the template to produce ion imprinted poly(anilineformaldehyde) (IIPAF) and non imprinted poly(aniline-formaldehyde) (NIPAF). The sorbent was characterized by Fourier Transform Infrared Spectroscopy and was used for solid phase extraction. The kinetics of the sorption was analyzed using the pseudo-first order and pseudo-second order kinetic models. The equilibrium adsorption data of Sr (II) on synthetic polymer were analyzed by Langmuir, Freundlich, Temkin and Redlich-Peterson models. The thermodynamic parameters were determined using the equilibrium constant values obtained at different temperatures. The results showed the negative values of Δ Gº and positive Δ Hº which indicated that the Sr (II) adsorption process is spontaneous and endothermic. The method was applied for strontium ions determination from Tap water samples.
Template and target information: strontium ions, Sr(II)
Author keywords: adsorption, Ion imprinted polymers, aniline-formaldehyde, Strontium (II), Kinetic