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Reference type: Journal
Authors: Rachkov A, McNiven S, Cheong SH, El'Skaya A, Yano K, Karube I
Article Title: Molecularly imprinted polymers selective for β-estradiol.
Publication date: 1998
Journal: Supramolecular Chemistry
Volume: 9
Issue: (4)
Page numbers: 317-323.
DOI: 10.1080/10610279808035001
Alternative URL: http://www.informaworld.com/10.1080/10610279808035001

Abstract: Polymers able to recognize the female steroid hormone, beta - estradiol, have been synthesized using molecular imprinting based on non-covalent interactions. A chromatographic study of the polymers demonstrated a strong dependence of the selectivity and strength of their interaction with analytes on the solvents used both as porogen and chromatographic mobile phase. Hydrogen bonding between the OH-group at C-17 of β-estradiol and methacrylic acid (the functional monomer of the polymer) plays a major role in the process of molecular recognition but hydrophobic and dipole-dipole interactions also contribute
Template and target information: 17β-estradiol

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