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Reference type: Journal
Authors: Li SJ, Luo YY, Whitcombe MJ, Piletsky SA
Article Title: A successive-reaction nanoreactor made of active molecularly imprinted polymer containing Ag nanoparticles.
Publication date: 2013
Journal: Journal of Materials Chemistry A
Volume: 1
Issue: (47)
Page numbers: 15102-15109.
DOI: 10.1039/C3TA13454G

Abstract: A successive-reaction nanoreactor made of a unique molecularly imprinted polymer containing Ag nanoparticles is reported. This molecularly imprinted polymer was fabricated using two well-coupled templates, i.e., 4-nitrophenyl acetate and 4-nitrophenol. The catalytic hydrolysis of the former by this nanoreactor led to the formation of the latter, which was further reduced by the nanoreactor to 4-aminophenol. Unlike reported nanoreactors, which usually promote one single reaction, this novel nanoreactor can run cascade reactions. The proposed integration of active molecularly imprinted polymers with metal nanoparticles opens a new opportunity for creating functional catalysts for complicated chemical processes
Template and target information: 4-nitrophenyl acetate, 4-nitrophenol


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