Paper 971

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Reference type: Journal
Authors: Ray A, Gupta SN
Article Title: Construction of template ligand sites in polymeric matrices with dithizone.
Publication date: 1997
Journal: Journal of Polymer Science Part A: Polymer Chemistry
Volume: 35
Issue: (17)
Page numbers: 3729-3734.
DOI: 10.1002/(SICI)1099-0518(199712)35:17<3729::AID-POLA12>3.0.CO;2-F

Abstract: Metal ion specific template ligand sites were developed by physically immobilizing dithizone molecules oriented according to a particular complex geometry in various polymeric films. Four polymeric systems, polystyrene, poly(methyl methacrylate), poly(vinyl chloride), and polycarbonate, were used for making template sites for Cu2+, Ni2+, Zn2+, and Co2+ ions. A high degree of specificity could be achieved independent of stability constants, though about half of the ligand sites were unavailable to the metal ions. (C) 1997 John Wiley & Sons, Inc

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