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Reference type: Journal
Authors: Vanossi D, Pigani L, Seeber R, Ferrarini P, Baraldi P, Fontanesi C
Article Title: Electropolymerization of ortho-phenylenediamine. Structural characterisation of the resulting polymer film and its interfacial capacitive behaviour.
Publication date: 2013
Journal: Journal of Electroanalytical Chemistry
Volume: 710
Page numbers: 22-28.
DOI: 10.1016/j.jelechem.2013.04.028
Alternative URL: http://www.sciencedirect.com/science/article/pii/S1572665713002129

Abstract: The physico-chemical characteristics of thin poly-(ortho-phenylenediamine) (PPD) films, obtained by electrochemical oxidation of the relevant monomer, are investigated using electrochemical, morphological and spectroscopic techniques. In particular, cyclic voltammetry and electrochemical impedance spectroscopy (EIS) techniques are used to collect information concerning the redox, conductivity and double layer capacitance properties of the PPD film. AFM imaging and Raman spectroscopy results are exploited to characterize the film structure. In this respect, Raman spectra of two possible PPD oligomers are calculated at the B3LYP/6-311G* * level of the theory
Template and target information: GA, gallic acid, SA, salicylic acid, 3IBA, 3-Hydroxybenzoic acid, 4IBA, 4-Hydroxybenzoic acid, CAT, catechol, AAP, 4-Acetamidophenol, AAS, acetylsalicylic acid, AN, nicotinic acid
Author keywords: Ortho-phenylenediamine, capacitive sensing, polymer, electropolymerization


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